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- W791886471 abstract "Two new [named salicifoxazines A (1) and B (2)] and six known dimeric tryptamine-derived alkaloids (3–8) were isolated from the leaves of Chimonanthus salicifolius. The new structures were established on the basis of extensive spectroscopic methods and chemical transformations. The absolute configuration of 1 was determined by the observed Cotton effects in its circular dichroism (CD) spectrum, whereas 2 is a pseudo-mesomer of 1. In fact, the first two naturally occurring asymmetric tetrahydro-1,2-oxazine-containing tryptamine-derived alkaloids 1 and 2 are diastereoisomers at C-3a/C-8a or at C-3a′/C-8a′. Compounds 1, 2, (−)-chimonanthine (3), and meso-chimonanthine (4) were found to show moderate cytotoxic effects against human colorectal carcinoma cells (SW-1116 and HCT-116) and/or gastric carcinoma cells (SGC-7901)." @default.
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- W791886471 date "2015-07-01" @default.
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- W791886471 title "Salicifoxazines A and B, new cytotoxic tetrahydro-1,2-oxazine-containing tryptamine-derived alkaloids from the leaves of Chimonanthus salicifolius" @default.
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- W791886471 doi "https://doi.org/10.1016/j.tetlet.2015.05.008" @default.
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