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- W79342537 abstract "The recombination dynamics of the primary radical ion pair state PF in bacterial reaction centers has been investigated with the particularly sensitive technique of Reaction Yield Detected Magnetic Resonance (RYDMR). Data are presented on the values of the exchange interaction J and the triplet recombination rate kT in the state PF of quinone-depleted reaction centers from Rb. sphaeroides (strain R26), Chloroflexus aurantiacus and Rb. capsulars (T=277K). The results show surprisingly little variations of J and kT among the species investigated. The recombination dynamics of PF has also been studied in genetically modified reaction centers from Rb. capsulatus where the tryptophane residue (M250) neighbouring both the bacteriopheophytin (BPhA) and the quinone (QA) acceptor had been replaced by either leucine, phenylalanine or glutamic acid via site-directed mutagenesis. A slight increase of J and kT in the order Leu → Phe → Trp → Glu is observed although the overall effect amounts to less than a factor of 2." @default.
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- W79342537 date "1990-01-01" @default.
- W79342537 modified "2023-09-27" @default.
- W79342537 title "Determination of the Exchange Interaction in the Primary Radical Ion Pair in Reaction Centers" @default.
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- W79342537 doi "https://doi.org/10.1007/978-94-009-0489-7_8" @default.
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