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- W793670698 abstract "In functionalized polybutadienes extended supramolecular junction zones are formed by self-aggregation of functional units via directed hydrogen bonds. The unusual 2H-NMR lineshapes as well as the large quadrupolar splittings indicate highly oriented network chains in the stretched samples. Angular dependent measurements and inversion-recovery experiments prove the uniaxiality of the deformation and the homogeneity of the polymer backbone dynamics. A quantitative analysis of the lineshapes according to present theories is not possible but the spectra can be understood assuming a gradient of orientation along individual network chains. For the highest strain ratios of λ>10 the 2H-NMR spectra give evidence of completely stretched chain segments which are located near the supramolecular clusters." @default.
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- W793670698 date "1995-05-05" @default.
- W793670698 modified "2023-10-02" @default.
- W793670698 title "Orientation Behavior of Thermoplastic Elastomers Studied by 2H-NMR Spectroscopy" @default.
- W793670698 doi "https://doi.org/10.1021/bk-1995-0597.ch013" @default.
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