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- W794130596 abstract "A complex [Cu(Phen)(5-Fu)2](NO3)2 was designed and synthesized with Cu (NO3)2, fluorouracil (5-Fu), and 1, 10-phenanthrotine (Phen) as the starting materials. The composition and chemical structure of resultant complex were analyzed by means of elemental analysis and infrared spectrometry. The interaction of [Cu(Phen)(5-Fu)2](NO3)2 with bovine serum albumin (BSA) in Tris-HCl buffer system (pH=6.50) was studied using fluorescence spectrometry. It was found that the interaction between the complex and BSA resulted in quenching of endogenous fluorescence of BSA. The quenching process could be described with static quenching mechanism, with quenching rate constant being 7.38×10^12 L•mol^(-1)•s^(-1), binding constant being 2.13×10^6 L•mol^(-1) and binding site number being 1.39. In the meantime, the complex could quench 95.4% of tryptophan (Trp) residue on the surface of BSA, showing promising potential as a candidate quenching agent for BSA." @default.
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- W794130596 date "2011-03-25" @default.
- W794130596 modified "2023-09-27" @default.
- W794130596 title "[Cu(Phen)(5-Fu)2](NO3)2配合物与牛血清白蛋白相互作用的荧光光谱研究" @default.
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