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• W796830785 abstract "The allylic amination of acetates and carbonates affords dehydro-β-aminoesters, which are useful precursors of biologically active compounds. The uncatalyzed reaction proceeds via a SN2′ mechanism. On the other hand, under palladium-catalyzed conditions, the reaction shows a strong solvent-dependent regiocontrol, affording exclusively one of the two possible regioisomers with complete transfer of chirality from the substrates to the products." @default.
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• W796830785 date "2008-05-17" @default.
• W796830785 modified "2023-09-23" @default.
• W796830785 title "Synthesis of Dehydro-β-amino esters <i>via</i> Highly Regioselective Amination of Allylic Carbonates" @default.
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• W796830785 doi "https://doi.org/10.1021/ol8006919" @default.
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