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- W798621777 abstract "The positions and interaction energies of framework atoms and water molecules of -exchanged zeolite A were calculated using some potential energy functions and an optimization program. The sum of interaction energies of framework atoms in dehydrated was approximately the same as those of thermally stable -or -exchanged zeolite A. Since ions can form good coordination bonds with framework oxygens even in dehydrated state, -exchanged zeolite A is considered to be thermally stable. The optimized positions of framework atoms and ions in this work are agreed well with the crystallographic data. Three groups of water molecules are found in hydrated -exchanged zeolite A; W(I) group of water molecules having only hydrogen bonds, W(II) group coordinated to ion, and W(III) group coordinated to ion. The average binding energy of each group of water molecules decrease in the order of W(III) > W(II) > W(I). The activation energies in the dehydration reaction of each group of water molecules increased in accordance with their binding energy." @default.
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- W798621777 date "1989-01-01" @default.
- W798621777 modified "2023-09-23" @default.
- W798621777 title "A Study on the Hydrated and Dehydrated $Mn^{2+}$-Exchanged Zeolite A" @default.
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