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- W80261776 abstract "The addition of DBPA to several phenylethylenes and terminal olefins has been studied. The reaction was found to proceed in boiling dichloromethane and was spontaneously or photolytically initiated depending on the structure and reactivity of the reactants. N-Bromo adducts, formed upon addition, could be reduced in situ with sodium bisulphite solution to give the corresponding diethyl N-(β-bromoalkyl)phosphoroamidates. Degradation of the latter with hydrogen chloride in benzene at room temperature afforded β-bromoamine hydrochlorides in pure state and reasonable overall yield. The observed regiospecificity for anti-Markovnikov addition, as proven by NMR and MS, is fully consistent with the radical-chain mechanism proposed for the reaction. This two-step sequences offers an easy access to β-bromoamines, the convenient precursors for an aziridine synthesis." @default.
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- W80261776 date "1981-01-01" @default.
- W80261776 modified "2023-09-24" @default.
- W80261776 title "N,N-Dihalophosphoramides—XIV" @default.
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- W80261776 doi "https://doi.org/10.1016/s0040-4020(01)98974-4" @default.
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