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- W803023740 abstract "In a previous study (Shinohara et al., Macromolecules, 2012, 45, 1398–1407), we have found that the annealing of injection molded polypropylene makes its macroscopic deformation fairly homogeneous despite the existence of a non-oriented core layer composed of the spherulite structure. In this study, to elucidate the mechanism for the homogeneous deformation behavior induced by annealing, we conduct a scanning microbeam x-ray scattering measurement of injection molded polypropylene under uniaxial stretching and analyze the structural change at each layer for the first time. It is observed that a plastic deformation of the crystals at each layer of the annealed sample is suppressed compared to that of an as-prepared sample. Furthermore, in the highly oriented layers of the annealed sample, homogeneous cavitation accompanied by the formation of the void with a narrow size distribution is observed. We conclude that the homogeneous cavitation induces strain hardening in the oriented layers, and that the hardened oriented layers dominate the total deformation behavior." @default.
- W803023740 created "2016-06-24" @default.
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- W803023740 date "2015-07-01" @default.
- W803023740 modified "2023-10-18" @default.
- W803023740 title "Macroscopically homogeneous deformation in injection molded polypropylene induced by annealing studied with microbeam X-ray scattering" @default.
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- W803023740 doi "https://doi.org/10.1016/j.polymer.2015.06.039" @default.
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