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- W804802008 abstract "During the homolytic reactions of or with -styrenes,-haloradicals are key intermediates. They are to be stabilized via three pathways; -cleavage, halogen transfer and telomerization. The three reaction paths are delicately controlled by the energetics of their formation and stabilization. When the formation of a -haloradical is accompanied by considerable excess of energy from an exothermic reaction, -cleavage is often dominant over the halogen transfer. On the other hand, if the radical forms via a reversible reaction, two processes become competitive. -Eliminated bromine atoms from -bromoradicals generate via may act as a better scavenger than Cl3CBr for the -bromoradicals. Different reactivities of chlorine, bromine and trichloromethyl radicals towards olefinic pi-bond are clarified in terms of the beat content of the addition reactions." @default.
- W804802008 created "2016-06-24" @default.
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- W804802008 date "1980-01-01" @default.
- W804802008 modified "2023-09-27" @default.
- W804802008 title "Mechanism and Products During the Homolytic Addition of CCl$_4$ and Cl$_3$CBr to $beta$-Halostyrenes" @default.
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