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- W80550314 abstract "This chapter discusses the group frequencies of alcohols and phenols in infrared (IR) and Raman spectra. The characteristic vibrations involving the O—H grouping are the stretching and bending modes of the O—H and C—Ο moieties. The vibrational spectra of phenol and substituted phenols are subject to extensive studies. The O—H stretching band in the IR spectrum is by far the most characteristic IR band of alcohols and phenols. The free O—H vibration occurs as a sharp IR band at above 3600 cm-1 while for the majority of condensed-phase samples, this O—H band is broadened and shifted to 3500–2500 cm−1 because of the various types of hydrogen bond formation. Characteristically, the presence of this sharp or broad band suggests a good possibility of the presence of the OH group. The chapter discusses the free O—H stretching in phenols. The O—H stretching frequencies of para- and meta-substituted phenols in vapor phase appear as a single band in the region of 3660–3642 cm−1." @default.
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- W80550314 date "1991-01-01" @default.
- W80550314 modified "2023-09-27" @default.
- W80550314 title "Alcohols and Phenols" @default.
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- W80550314 doi "https://doi.org/10.1016/b978-0-08-057116-4.50010-9" @default.
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