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- W80743065 abstract "Base sites and photoactive sites of fine particles of MgO dispersed on silica have been studied. In order to control the population of the coordinatively unsaturated surface Mg and O ions (Mgcus and Ocus), some samples including magnesium oxide fine particles were prepared. These samples are well defined and have each specific amount of CUS ions by changing amount of loading on silica. Thus prepared samples were free from F+ center trapping an electron which have been proposed to be photoactive sites. From the correlation between the population of CUS ion pairs and the rate of photooxidation, we have concluded that the catalytic active sites for CO photooxidation are (Mgcus-Ocus) pairs. Since a good relationship between the amount of base sites where CO2 molecules are chemisorbed and the rate of photooxidation of CO is observed, base sites and photoactive sites are considered to be identical." @default.
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- W80743065 date "1994-01-01" @default.
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- W80743065 title "4.16 Base Sites of Magnesium Oxide Dispersed on Silica as Active Sites for CO Photooxidation" @default.
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- W80743065 doi "https://doi.org/10.1016/s0167-2991(08)61861-3" @default.
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