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- W808890322 abstract "Passivation of steel in concrete is due to a two component system consisting of a portlandite layer and a thin pH stabilised iron oxide/hydroxide film on the surface of the metal. Chloride ions in concrete breakdown the passivity of the system by dissolution of the portlandite layer followed by debonding of the passive film. The ratio of iron to chloride across the debonded film was measured using scanning electron microscope energy dispersive x-ray microprobe (SEM-EDS) and was found to increase exponentially toward the insitu passive film. Some areas of chemically unaffected passive film were also found to be disbonded supporting the view that a physical process also operates during disruption. This has been attributed to the internal film pressure.(A) For the covering abstract of the conference see IRRD 831449." @default.
- W808890322 created "2016-06-24" @default.
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- W808890322 date "1990-01-01" @default.
- W808890322 modified "2023-09-27" @default.
- W808890322 title "THE BREAKDOWN OF THE PASSIVE FILM ON HIGH YIELD MILD STEEL BY CHLORIDE IONS. CORROSION OF REINFORCEMENT IN CONCRETE. PAPERS PRESENTED AT THE THIRD INTERNATIONAL SYMPOSIUM ON CORROSION OF REINFORCEMENT IN CONCRETE CONSTRUCTION, BELFRY HOTEL, WISHAW, WARWICKSHIRE, MAY 21-24, 1990" @default.
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