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• W809316107 abstract "[EN] Zeolites are microporous crystalline materials showing channels and cavities of molecular dimensions in its interior. The main advantage of these materials is their high thermal and chemical stability as well as the possibility to change the topology and dimensions of the channels and cavities.The main goal of this thesis is to obtain new microporous materials (zeolites) and to widen the composition range of some existing materials, using high-throughput techniques of synthesis and characterization.Four families of structure directing agents (SDAs) are synthesized to obtain these microporous materials and each family is formed by quaternary tetraalkylammonium cations. The size and the volume of the members of each SDA family are increased to carry out a study on how it affects this increase on the type of zeolite that crystallizesTaking into account the importance of each of the various parameters that influence on the hydrothermal synthesis of zeolites and trying to cover all the possible range of composition, a factorial design of experiments for each obtained and characterized SDA is performed. The materials of interest obtained in these experiments are subjected to an exhaustive characterization, in order to determine its structure and properties.Known materials such as zeolites ITQ-3, ITQ-43 and ITQ-44 have been obtained with the SDAs used. But the most important thing of this thesis has been obtaining two new materials, which we refer to as ITQ-57 and ITQ-60. The structure of the zeolite ITQ-60 is completely determined and we can conclude that it is an intergrown material, formed by two layers and presenting a two-dimensional system of 10 x 12 MR channels. On the other hand, the structure of the zeolite ITQ-57 is in its final stages of definition, but we are able to determine is that it presents a large orthorhombic unit cell.We must also mention the obtaining of an optimized synthesis method of the chiral zeolite SU-32. This zeolite has been synthesized as a racemic mixture with a chiral SDA. Using theoretical calculations it has been found that every one of the enantiomers of the SDA is able to lead to the formation of each one of the enantiomers of chiral zeolite. The last step is to synthesize each enantiomer of the SDA separately, allowing us to obtain the two chiral zeolites.; [ES] Las zeolitas son materiales cristalinos microporosos que presentan canales y cavidades de dimensiones moleculares en su interior. La principal ventaja de estos materiales es su elevada estabilidad termica y quimica, asi como la posibilidad de poder variar la topologia y dimensiones de los canales y cavidades.El principal objetivo de esta tesis doctoral es la obtencion de nuevos materiales microporosos (zeolitas) y ampliar el rango de composicion de alguno ya existente, empleando tecnicas de sintesis y caracterizacion de alta capacidad.Para la obtencion de estos materiales microporosos se sintetizan cuatro familias de agentes directores de estructura (ADEs), formadas por cationes tetraalquilamonio cuaternarios. En…" @default.
• W809316107 created "2016-06-24" @default.
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• W809316107 date "2015-12-29" @default.
• W809316107 modified "2023-09-26" @default.
• W809316107 title "Síntesis de Nuevos Materiales Microporosos Mediante Técnicas High-Throughput." @default.
• W809316107 doi "https://doi.org/10.4995/thesis/10251/59230" @default.
• W809316107 hasPublicationYear "2015" @default.
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