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- W80943072 abstract "The equilibrium diagrams of the binary systems of sulphuric acid with nitromethane and with o-, m- and p-nitrotoluene have been investigated. It has been shown that addition compounds of the type 1 : 1 are formed in these systems, analogous to the compound sulphuric acid–nitrobenzene (Cherbuliez Helv. Chim. Acta 1923 6 281; and Masson J. Chem. Soc. 1931 3201). The formation of these addition compounds is due to hydrogen bonding between the components, rather than to proton transfer. Their stability in the crystalline phase seems to be contradictory to the known basicities of mononitrocompounds (Gillespie and Solomons J. Chem, Soc. 1957 1796), because of the effect of temperature on the equilibria in the liquid phase." @default.
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- W80943072 date "1959-01-01" @default.
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- W80943072 title "HYDROGEN BONDING OF NITROCOMPOUNDS WITH SULPHURIC ACID PART I EQUILIBRIUM DIAGRAMS OF BINARY SYSTEMS OF NITROMETHANE AND o-, m- AND p-NITROTOLUENE WITH SULPHURIC ACID" @default.
- W80943072 doi "https://doi.org/10.1016/b978-0-08-009140-2.50059-2" @default.
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