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- W813846543 abstract "Abstract The synthesis and characterisation of three metal bisdithiolene complexes based on the recently reported highly extended ligand incorporating fused tetrathiafulvalene and pyrazine moieties, [M(pztdt)2], M = Ni, Pd, Pt and pztdt = pyrazinetetrathiafulvalenedithiolate, are reported. These complexes were obtained under anaerobic conditions as crystals of dianionic tetrabutylammonium salts. The crystal structures of Ni and Pd complexes as determined by single crystal X-ray diffraction confirm the ability of these molecules to established interactions with their neighbours through the pyrazine moieties. These dianionic complexes easily undergo oxidations to their monoanionic and neutral states, with a narrow range of stability for the monoanionic and an extended one for the neutral forms that is rather insoluble in common solvents." @default.
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- W813846543 date "2015-08-01" @default.
- W813846543 modified "2023-10-18" @default.
- W813846543 title "Complexes with pyrazine-tetrathiafulvalene-dithiolate (pztdt) ligand [M(pztdt)2], M = Ni, Pd, Pt; Synthesis and characterisation" @default.
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- W813846543 doi "https://doi.org/10.1016/j.inoche.2015.06.001" @default.
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