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- W814059558 abstract "We report the synthesis and photophysical properties of a novel tricarbonyl rhenium(I) complex having a (dimesityl)boryldurylethynyl (DBDE) group at the 4-position of a 2,2′-bipyridine (bpy) ligand, fac-[Re(CO)3(DBDE-bpy)Br] = ReBbpy, and discuss the diimine ligand structure effects on the spectroscopic and photophysical properties of the complex by comparing with those of the relevant 4-DBDE-1,10-phenanthroline (phen) type complex: fac-[Re(CO)3(DBDE-phen)Br] = ReBphen. The present study demonstrated that ReBbpy showed smaller DBDE effects on the spectroscopic and photophysical properties compared with ReBphen, whose origin was discussed in terms of the redox, absorption/emission, and time-dependent density functional theory calculation data on the complexes." @default.
- W814059558 created "2016-06-24" @default.
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- W814059558 date "2015-12-01" @default.
- W814059558 modified "2023-10-15" @default.
- W814059558 title "Diimine ligand structure effects on photophysical properties of tricarbonyl rhenium(I) complexes having arylborane charge transfer units" @default.
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- W814059558 doi "https://doi.org/10.1016/j.jphotochem.2015.05.034" @default.
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