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- W814892240 abstract "The studies presented in this thesis report on the use of the anionic polymerization with two different methodologies of monomer activation aiming to control the reactivity of monomers and/or growing species for the synthesis of polyethers and polyamide-3. New magnesium/aluminium active systems efficient for the anionic ringopening polymerization of substituted epoxides are proposed and developed. Cross-linkable polyethers were also synthesized by using the combination of tetraoctylammonium bromide with triisobutylaluminum. Furan groups or double bonds were introduced as pendant or inchain functions respectively in polyether-based materials. The so-formed polymers were cross-linked using reversible Diels-Alder reaction between furan and maleimide, and vulcanization for the double bonds. Finally, we investigated the mechanism of the hydrogentransfer polymerization of acrylamide in bulk conditions as a sustainable route to get polyamide-3." @default.
- W814892240 created "2016-06-24" @default.
- W814892240 creator A5014301598 @default.
- W814892240 date "2015-12-15" @default.
- W814892240 modified "2023-09-26" @default.
- W814892240 title "Polyethers and polyamide-3 synthesis by monomer activated anionic polymerization" @default.
- W814892240 hasPublicationYear "2015" @default.
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