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- W81574647 abstract "Summary Some solutes present in secondary effluents are oxidized by a direct reaction of molecular ozone during an ozonation process. These oxidations are very selective. Their rates can be calculated from the concentration of ozone and the 2nd order reaction rate constants measured for specified solutes in water. Part of the ozone decomposes in water, leading to the formation of secondary oxidants. Of these, the OH. radicals easily oxidize even inert types of organic solutes, but they are non-selective and become consumed by fast reactions. The amount of decomposed ozone required to achieve a desired degree of elimination of a specified solute by OH. radicals is therefore proportional to the sum of the rates with which the sum of solutes present in the wastewater consumes OH. radicals. At elevated pH values, even carbonate ions and free ammonia contribute to this OH. radical consumption. The yield of the oxidations and its dependence on water composition can be estimated from reaction-rate constants." @default.
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- W81574647 date "1979-01-01" @default.
- W81574647 modified "2023-10-09" @default.
- W81574647 title "OZONE INITIATED OXIDATIONS OF SOLUTES IN WASTEWATER: A REACTION KINETIC APPROACH" @default.
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