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- W8168599 abstract "The title compound, [Cu(C5H10NO3)2], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethylaminoethanol in acetonitrile, in air. The molecule is centrosymmetric with two monodeprotonated N-(2-hydroxyethyl)-N-methylglycines coordinated to the metal in a tridentate mode, giving a bicyclic chelate with two distorted five-membered rings. The CuII ion possesses a distorted octahedral geometry, with the N and the O atoms from the carboxylate groups in the equatorial plane. In the crystal structure, intermolecular O—H⋯O hydrogen-bonding interactions from the alkoxide functions of the ligand through the inversion centre form columns of molecules propagated along the a axis." @default.
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- W8168599 date "2008-11-22" @default.
- W8168599 modified "2023-09-25" @default.
- W8168599 title "Bis[<i>N</i>-(2-hydroxyethyl)-<i>N</i>-methylglycinato]copper(II)" @default.
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- W8168599 doi "https://doi.org/10.1107/s1600536808037793" @default.
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