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- W81775796 abstract "Abstract The key factor that allowed the outstanding development of polyolefins has been the Ziegler-Natta catalysis that played and is still playing an innovative role in this field. More and more sophisticated new catalysts have made possible advanced polymerization technologies, improved product grades and a broader range of applications, through a better understanding of the relationships among the catalyst architecture, the micro and macrostructure of the polymer and its properties. Aiming to widen the “property envelope” of polypropylene we have to improve the followig aspects: i) polymer architecture control ii) polymer microstructure control iii) modification of the surface properties iiii) modification of the rheological properties. The guidelines that we have followed, by using heterogeneous MgC1 2 based catalysts, to overcome these problems are reported." @default.
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- W81775796 date "1994-01-01" @default.
- W81775796 modified "2023-10-14" @default.
- W81775796 title "13. New Heterogeneous Catalysts for Polyolefins" @default.
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- W81775796 doi "https://doi.org/10.1016/s0167-2991(08)63029-3" @default.
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