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- W82001610 abstract "Abstract Mo(O)(O 2 ) 2 L′L″ [L′ = H 2 O, L″ = hexamethylphosphoramide (HMPA) 1 ; L′ = L″ = triphenylphosphine oxide (TPPO) 2 ] reacts with primary aliphatic amines to give cis-dioxoperoxo complexes, Mo(O) 2 (O 2 )(RNH 2 ) 2 [R = C 6 H 5 CH 2 3 , 2,4-Cl 2 -C 6 H 3 CH 2 4 , 2,4-(OCH 3 ) 2 -C 6 H 3 CH 2 5 , C 6 H 11 6 ; 4-Cl-C 6 H 4 CH 2 7 , 2-Cl-C 6 H 4 CH 2 8 ] and the corresponding oximes. Secondary aliphatic amines, 1,2,3,4-tetrahydroisoquinoline, dipropylamine and dibenzylamine, give the analogous complexes and the corresponding Schiff bases. Complexes 3 and 6 act as catalysts in the oxidation respectively of benzylamine to benzaldehyde oxime and of cyclohexylamine to cyclohexanone oxime with H 2 O 2 at room temperature." @default.
- W82001610 created "2016-06-24" @default.
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- W82001610 date "1991-01-01" @default.
- W82001610 modified "2023-09-27" @default.
- W82001610 title "Oxidation of primary and secondary aliphatic amines by Mo(O)(O2)2L′L″ (L′ = H2O, L″ = hexamethylphosphoramide)" @default.
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- W82001610 doi "https://doi.org/10.1016/s0167-2991(08)62873-6" @default.
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