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• W821741976 endingPage "169" @default.
• W821741976 startingPage "156" @default.
• W821741976 abstract "Ten coordination compounds, namely {[Cd(L)(die)]·2/3H2O}n (1), [Cd(L)(dib)]n (2), [Cd(L)(bmimb)]n (3), {[Cd(L)(bimb)]·1/2EtOH}n (4), [Zn(L)(bimb)]n (5), [Co(L)(bimb)]n (6), {[Cd(L)(phen)]·EtOH}n (7), [Cu(L)(phen)]n (8), [Zn(L)(mtpy)]n (9) and [Ni(L)(mtpy)]·1/2H2O (10) (H2L = 4′-((2-carboxyphenoxy)methyl)biphenyl-2-carboxylic acid, die = 1,2-di(1H-imidazol-1-yl)ethane, dib = 1,4-di(1H-imidazol-1-yl)butane, bmimb = 1,4-bis((2-methyl-1H-imidazol-1-yl)methyl)benzene, bimb = 1,4-bis((1H-imidazol-1-yl)methyl)benzene, phen = 1,10-phenanthroline and mtpy = 4′-(4-methylphenyl)-2,2′:6′,2″-terpyridine), have been solvothermally synthesized. These compounds were characterized by X-ray crystallography, elemental analysis, infrared spectra (IR) and powder X-ray diffraction (PXRD). In compounds 1–3, similar dimeric [Cd2(L)2] units are connected by different N-donor ligands to form diverse architectures. Strikingly, compound 3 displays a 2D → 3D interdigitated framework. Compounds 4–6 are essentially isostructural and reveal 2D sheet structures. Compound 7 shows a 2D 44-sql network stabilized by π–π interactions between the pyridine rings of the phen ligands. Compound 8 exhibits a 3D supramolecular architecture constructed from a 1D chain via π–π interactions. Compound 9 possesses a 1D chain structure, which is further extended into a 2D supramolecular layer through hydrogen-bonding interactions. Compound 10 displays a [Cd2(L)2(mtpy)2] dimeric structure. Adjacent dimers further interact through hydrogen-bonding interactions to afford a 1D supramolecular chain. Moreover, the luminescent properties of 1–5, 7 and 9 have also been investigated in this work." @default.
• W821741976 created "2016-06-24" @default.
• W821741976 creator A5003769106 @default.
• W821741976 creator A5005206290 @default.
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• W821741976 creator A5037824478 @default.
• W821741976 creator A5058734476 @default.
• W821741976 creator A5060445786 @default.
• W821741976 creator A5079212063 @default.
• W821741976 date "2015-10-01" @default.
• W821741976 modified "2023-10-15" @default.
• W821741976 title "Ten coordination compounds constructed by 4′-((2-carboxyphenoxy)methyl)biphenyl-2-carboxylic acid and various N-donor ligands: Syntheses, structures and luminescent properties" @default.
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