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- W822195196 abstract "Abstract A series of nickel catalysts were prepared by the impregnation and co-precipitation methods and characterized by X-ray diffraction, nitrogen physisorption, and H 2 temperature-programmed reduction. The effects of nickel loading, calcination temperature, reaction temperature, support modification and cobalt oxide addition on the catalytic activity and selectivity to H 2 in the steam reforming of ethylene glycol were investigated. The results indicate that the nickel catalyst prepared by co-precipitation has smaller particle size and relatively higher activity in comparison with the catalyst prepared by impregnation. Adding a small amount of cobalt oxide to the Ni/CeO 2 catalysts can enhance the catalytic activity; over the Ni-Co bimetallic catalyst, the yield of hydrogen reaches 72.6%. Modifying CeO 2 with Al 2 O 3 , TiO 2 and ZrO 2 also has a certain influence on the catalytic activity and the Ni/CeO 2 -Al 2 O 3 catalyst exhibits the highest activity, with an ethylene glycol conversion of 94% to gaseous products and a hydrogen yield of 67%. However, Ni/CeO 2 -SiO 2 shows a very low activity in spite of its large surface area and pore volume." @default.
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- W822195196 date "2015-05-01" @default.
- W822195196 modified "2023-09-26" @default.
- W822195196 title "Hydrogen production from steam reforming of ethylene glycol over supported nickel catalysts" @default.
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