Matches in SemOpenAlex for { <https://semopenalex.org/work/W822897617> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W822897617 endingPage "661" @default.
- W822897617 startingPage "658" @default.
- W822897617 abstract "The gas-phase nucleophilic substitution reaction of pentafluoroanisole with and nucleophiles have been studied theoretically using the AM1 method. Three reaction channels, , IPSO and (scheme 1), are all very exothermic so that all are accessible despite the varying central energy barriers which are much lower than the reactants level. In the IPSO and channels, the reactants form directly a stable ,-anion complex which proceeds to form a proton transfer complex via a transition barrier corresponding to a loose -type complex with the F-(or ) leaving group. Due to a greater number of probable reaction sites available for compared to the other two processes, the channel is favored as experimentally observed." @default.
- W822897617 created "2016-06-24" @default.
- W822897617 creator A5000714813 @default.
- W822897617 creator A5022650579 @default.
- W822897617 creator A5091745829 @default.
- W822897617 date "1991-01-01" @default.
- W822897617 modified "2023-09-24" @default.
- W822897617 title "Theoretical Studies on the Gas-Phase Nucleophilic Aromatic Substitution Reaction" @default.
- W822897617 hasPublicationYear "1991" @default.
- W822897617 type Work @default.
- W822897617 sameAs 822897617 @default.
- W822897617 citedByCount "0" @default.
- W822897617 crossrefType "journal-article" @default.
- W822897617 hasAuthorship W822897617A5000714813 @default.
- W822897617 hasAuthorship W822897617A5022650579 @default.
- W822897617 hasAuthorship W822897617A5091745829 @default.
- W822897617 hasConcept C111185830 @default.
- W822897617 hasConcept C121332964 @default.
- W822897617 hasConcept C135731615 @default.
- W822897617 hasConcept C145148216 @default.
- W822897617 hasConcept C147597530 @default.
- W822897617 hasConcept C147789679 @default.
- W822897617 hasConcept C155647269 @default.
- W822897617 hasConcept C159467904 @default.
- W822897617 hasConcept C161790260 @default.
- W822897617 hasConcept C178790620 @default.
- W822897617 hasConcept C178907741 @default.
- W822897617 hasConcept C185592680 @default.
- W822897617 hasConcept C199360897 @default.
- W822897617 hasConcept C2778220771 @default.
- W822897617 hasConcept C3020013744 @default.
- W822897617 hasConcept C41008148 @default.
- W822897617 hasConcept C44280652 @default.
- W822897617 hasConcept C45119746 @default.
- W822897617 hasConcept C54516573 @default.
- W822897617 hasConcept C62520636 @default.
- W822897617 hasConcept C75473681 @default.
- W822897617 hasConcept C9061509 @default.
- W822897617 hasConceptScore W822897617C111185830 @default.
- W822897617 hasConceptScore W822897617C121332964 @default.
- W822897617 hasConceptScore W822897617C135731615 @default.
- W822897617 hasConceptScore W822897617C145148216 @default.
- W822897617 hasConceptScore W822897617C147597530 @default.
- W822897617 hasConceptScore W822897617C147789679 @default.
- W822897617 hasConceptScore W822897617C155647269 @default.
- W822897617 hasConceptScore W822897617C159467904 @default.
- W822897617 hasConceptScore W822897617C161790260 @default.
- W822897617 hasConceptScore W822897617C178790620 @default.
- W822897617 hasConceptScore W822897617C178907741 @default.
- W822897617 hasConceptScore W822897617C185592680 @default.
- W822897617 hasConceptScore W822897617C199360897 @default.
- W822897617 hasConceptScore W822897617C2778220771 @default.
- W822897617 hasConceptScore W822897617C3020013744 @default.
- W822897617 hasConceptScore W822897617C41008148 @default.
- W822897617 hasConceptScore W822897617C44280652 @default.
- W822897617 hasConceptScore W822897617C45119746 @default.
- W822897617 hasConceptScore W822897617C54516573 @default.
- W822897617 hasConceptScore W822897617C62520636 @default.
- W822897617 hasConceptScore W822897617C75473681 @default.
- W822897617 hasConceptScore W822897617C9061509 @default.
- W822897617 hasIssue "6" @default.
- W822897617 hasLocation W8228976171 @default.
- W822897617 hasOpenAccess W822897617 @default.
- W822897617 hasPrimaryLocation W8228976171 @default.
- W822897617 hasRelatedWork W1913196861 @default.
- W822897617 hasRelatedWork W1975908384 @default.
- W822897617 hasRelatedWork W1985304109 @default.
- W822897617 hasRelatedWork W1985422608 @default.
- W822897617 hasRelatedWork W2035131275 @default.
- W822897617 hasRelatedWork W2035729914 @default.
- W822897617 hasRelatedWork W2045438380 @default.
- W822897617 hasRelatedWork W2055752132 @default.
- W822897617 hasRelatedWork W2086674114 @default.
- W822897617 hasRelatedWork W2092007804 @default.
- W822897617 hasRelatedWork W2153325853 @default.
- W822897617 hasRelatedWork W2326211400 @default.
- W822897617 hasRelatedWork W2376554414 @default.
- W822897617 hasRelatedWork W2390251700 @default.
- W822897617 hasRelatedWork W2460439740 @default.
- W822897617 hasRelatedWork W2765849332 @default.
- W822897617 hasRelatedWork W2802686391 @default.
- W822897617 hasRelatedWork W3010951754 @default.
- W822897617 hasRelatedWork W836078409 @default.
- W822897617 hasRelatedWork W910229829 @default.
- W822897617 hasVolume "12" @default.
- W822897617 isParatext "false" @default.
- W822897617 isRetracted "false" @default.
- W822897617 magId "822897617" @default.
- W822897617 workType "article" @default.