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- W825697890 abstract "A new coordination complex [Cu(Ⅱ)(DETA)]3[Cr(CN)6]2·5H2O (DETA=diethylenetriamine) was synthesized, its crystal structure and magnetic properties were determined. The crystal crystallizes in monoclinic space group P21/c, with unit cell constants a=2.0566(7) nm, b=1.4407(5) nm, c=1.513 3(5) nm, β=95.996(6)°, and V=4.459(3) nm^3, Z=4, D,,=1.499 g·cm^-3, F(000)=2 060,μ(Mo Kα)=1.936 mm^-1, R1=0.052 3, wR2=0.106 2. The structure consists of a one-dimensional chain of [Cu(DETA)]2[Cr(CN)6]^+ and binuclear [Cu(DETA)][Cr(CN)6]^-. The coordination geometries around Cu^2+ atoms are distorted square-based pyramidal and distorted square, respectively.Magnetism studies show that there are ferromagnetic interactions between Cu^2+ and Cr^3+ ions. CCDC: 272213." @default.
- W825697890 created "2016-06-24" @default.
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- W825697890 date "2005-01-01" @default.
- W825697890 modified "2023-09-24" @default.
- W825697890 title "[Cu（II）（DETA）]3[Cr（CN）6]2·5H2O（DETA=二乙烯三胺）" @default.
- W825697890 hasPublicationYear "2005" @default.
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