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- W826856623 abstract "1 The electrochemical reduction of fumaric acid was studied on Hg, Hg/l%Bi amalgam, and Bi at 60°C in acidic solutions of various pH ranging from 0.3 to 3.7. The fumaric acid was reduced to succinic acid with high efficiency on each electrode. The steady state kinetic parameters included Tafel slopes of ca. 2.3 RT/F and first order concentration dependences for both undissociated + fumaric acid and H . Transient measurements indicated low coverages of adsorbed fumaric acid and no adsorbed hydrogen species in the potential region of the reaction. A reaction mechanism is proposed which involves a chemical rate determining step between an adsorbed fumaric acid molecule(that has added an electron} and a non-adsorbed H+. INTRODUCTION studies of the electrolytic reduction of fumaric acid appearing in the literature have mostly concerned current" @default.
- W826856623 created "2016-06-24" @default.
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- W826856623 date "1972-01-01" @default.
- W826856623 modified "2023-09-27" @default.
- W826856623 title "The elec trochemical reduction of fumaric acid on Hg-Bi cathodes" @default.
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- W826856623 hasPublicationYear "1972" @default.
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