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- W82715432 abstract "The design of highly ordered supramolecular structures has gained more and more interest within the last few decades. The concept of self-assembly chemistry takes a key position in this field and a multitude of supramolecular compounds have been synthesized by combining simple building blocks to two- and three-dimensional structures [1–3]. Due to their electronic and steric versatility aromatic N-heterocycles play a prominent role as classical ligands in coordination compounds, [4,5] as bridging ligands in binuclear derivatives [6–8] and as building blocks for supramolecular compounds [9–17]. Beyond their capability to connect metal centers by forming ligand to metal bonds they provide the opportunity of π-backbonding and thereby may affect delocalization and transport of electrons [18]. Compared with the highly developed late transition metal supramolecular chemistry, only a few attempts have been made to use the well defined coordination modes and the reducing properties of early transition metals [19,20]." @default.
- W82715432 created "2016-06-24" @default.
- W82715432 creator A5027772285 @default.
- W82715432 date "2008-01-01" @default.
- W82715432 modified "2023-09-26" @default.
- W82715432 title "Titanium-Based Molecular Architectures Formed by Self-Assembled Reactions" @default.
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- W82715432 doi "https://doi.org/10.1007/978-3-540-72675-3_2" @default.
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