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- W828137816 abstract "Cadmium gained its name from the Greek word for kadmeia which is an ancient name for Zn(II) oxide [1]. Cadmium is similar in some ways to Zn(II) and the most common oxidation state is Cd(II). In coordination compounds Cd(II) is often found hepta-coordinate [2, 3]. Cd(II) is often used as a sensor for structural and mechanistic studies of proteins in which Zn(II) is substituted by Cd(II) in their active centers. Often a higher hydrolytic activity is found than in the corresponding Zn(II) enzymes and complexes [2]. This might be due to the increased number of ligands (nucleophiles, substrate) that are possible to bind and exchange at the Cd(II) center. 113Cd NMR spectroscopy is a method used for structure elucidation in biological, inorganic and organometallic cadmium-containing samples [5, 6].KeywordsMass Spectrometry ExperimentMethyl Parathion HydrolaseAcetate LigandTerminal WaterTerminal Water MoleculeThese keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves." @default.
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- W828137816 date "2014-01-01" @default.
- W828137816 modified "2023-09-25" @default.
- W828137816 title "Mechanistic Studies of Cd(II) Complexes as Phosphoesterase and Metallo-β-lactamase Models" @default.
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- W828137816 doi "https://doi.org/10.1007/978-3-319-06629-5_5" @default.
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