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W8282652 abstract "Dans l'ammoniac liquide, l'iode existe au degré d'oxydation (1+)sous trois formes NH2I, Iam+ et NI3, x NH3(s). Le complexe NH2I est peu stable, sa formation en quantité notable est observée uniquement à basse température (−78°C) en milieu amidure. L'ion Iam+ est stable dans un plus grand domaine de température (−78°C; −40°C). En présence d'un excès d'iode, il apparaît à côte de l'ion Iam+ l'espèce NI3, xNH3(s) dont la couleur est fonction de la température. Evidence is presented for the formation of the following iodine (1+) species in liquid ammonia: NH2I, I+, and an insoluble compound NI3, xNH3(s). The transient NH2I complex can be observed only at low temperature (−78°C) in concentrated amide medium. The I+ cation is stable in a wide range of temperatures (−78°C to −40°C). Addition of an excess of iodine to a solution of I+ results in the formation of an in soluble NI3, xNH3 compound, the color of which is temperature dependent." @default.
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W8282652 date "1971-06-01" @default.
W8282652 modified "2023-10-18" @default.
W8282652 title "Ammonaic liquide" @default.
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W8282652 doi "https://doi.org/10.1016/s0022-0728(71)80053-0" @default.
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