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- W830248736 abstract "Three new dimethyl aluminium complexes 1–3 containing aminophenol ligands (LAlMe2, where L1 = diethylaminophenoxide, L2 = diisopropylaminophenoxide and L3 = piperidinophenoxide) were synthesized and characterized by different spectroscopic techniques and elemental analysis. The solid state structure of 1 was determined by single crystal X-ray diffraction studies. The data revealed that 1 possesses as a distorted tetrahedral geometry around the aluminium centre. The catalytic activities of these complexes towards the ring opening polymerization (ROP) of rac-lactide (rac-LA) and L-lactide (L-LA) were examined and good efficiency with controlled number average molecular weight (Mn) and narrow molecular weight distributions (MWDs) were achieved. Homonuclear decoupled 1H NMR spectrum confirms the heterotactic enrichment in the PLA obtained from rac-LA. The MALDI-TOF mass and 1H NMR spectra of low molecular weight oligomers revealed that the aminophenoxide ligand initiates the ROP. The geometries of all the complexes were optimized at B3LYP/LANL2DZ level and DFT calculations were carried out in order to establish the relation between the reactivity and the HOMO–LUMO energy gap." @default.
- W830248736 created "2016-06-24" @default.
- W830248736 creator A5025336463 @default.
- W830248736 creator A5033771847 @default.
- W830248736 creator A5067129564 @default.
- W830248736 date "2015-09-01" @default.
- W830248736 modified "2023-10-14" @default.
- W830248736 title "Aluminium complexes bearing N,O-aminophenol ligands as efficient catalysts for the ring opening polymerization of lactide" @default.
- W830248736 cites W1963816831 @default.
- W830248736 cites W1968846725 @default.
- W830248736 cites W1970286837 @default.
- W830248736 cites W1971980419 @default.
- W830248736 cites W1972044984 @default.
- W830248736 cites W1973725652 @default.
- W830248736 cites W1978038890 @default.
- W830248736 cites W1981346049 @default.
- W830248736 cites W1982906494 @default.
- W830248736 cites W1985570466 @default.
- W830248736 cites W1987396342 @default.
- W830248736 cites W1987666849 @default.
- W830248736 cites W1988783664 @default.
- W830248736 cites W1993309120 @default.
- W830248736 cites W1993851222 @default.
- W830248736 cites W1998012119 @default.
- W830248736 cites W2008708918 @default.
- W830248736 cites W2010697133 @default.
- W830248736 cites W2011072774 @default.
- W830248736 cites W2012613055 @default.
- W830248736 cites W2015428560 @default.
- W830248736 cites W2015891510 @default.
- W830248736 cites W2016413075 @default.
- W830248736 cites W2016503884 @default.
- W830248736 cites W2017641312 @default.
- W830248736 cites W2020574670 @default.
- W830248736 cites W2022523714 @default.
- W830248736 cites W2023890117 @default.
- W830248736 cites W2024262973 @default.
- W830248736 cites W2026175751 @default.
- W830248736 cites W2027210775 @default.
- W830248736 cites W2031240265 @default.
- W830248736 cites W2044711120 @default.
- W830248736 cites W2046387630 @default.
- W830248736 cites W2047814327 @default.
- W830248736 cites W2050006124 @default.
- W830248736 cites W2059432899 @default.
- W830248736 cites W2061088416 @default.
- W830248736 cites W2062855873 @default.
- W830248736 cites W2065389010 @default.
- W830248736 cites W2068559689 @default.
- W830248736 cites W2073366260 @default.
- W830248736 cites W2074789866 @default.
- W830248736 cites W2079407133 @default.
- W830248736 cites W2081542570 @default.
- W830248736 cites W2082264584 @default.
- W830248736 cites W2084031965 @default.
- W830248736 cites W2086946175 @default.
- W830248736 cites W2088006724 @default.
- W830248736 cites W2092296216 @default.
- W830248736 cites W2106343980 @default.
- W830248736 cites W2108463100 @default.
- W830248736 cites W2109254142 @default.
- W830248736 cites W2113701650 @default.
- W830248736 cites W2114073801 @default.
- W830248736 cites W2124720894 @default.
- W830248736 cites W2138892730 @default.
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- W830248736 cites W2153019818 @default.
- W830248736 cites W2164004858 @default.
- W830248736 cites W2165110913 @default.
- W830248736 cites W2169039177 @default.
- W830248736 cites W2170686804 @default.
- W830248736 cites W2313206307 @default.
- W830248736 cites W2314638203 @default.
- W830248736 cites W2318700678 @default.
- W830248736 cites W2319185509 @default.
- W830248736 cites W2321655997 @default.
- W830248736 cites W2324342538 @default.
- W830248736 cites W2325076286 @default.
- W830248736 cites W2325772550 @default.
- W830248736 cites W2332520403 @default.
- W830248736 cites W2335632823 @default.
- W830248736 doi "https://doi.org/10.1016/j.eurpolymj.2015.07.025" @default.
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