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- W8304782 abstract "Ru/MoO 3 catalysts containing 0.5, 1 and 2 wt% Ru have been prepared using two kinds of MoO 3 , and their reduction by H 2 has been followed by XRD and TGA. Ru catalyses the reduction of the MoO 3 ; a hydrogen Mo bronze is first formed, and reduction to Mo metal is complete at 773 K. Catalysts reduced at 623 K or above give ∼ 25-30% of C 1 -C 3 alcohols from syngas; the proportion of C 2 or C 3 alcohols decreases with reduction temperature, and when this is 723 K only methanol is formed. Reduced MoO x species promote alcohol synthesis either through an SMSI effect or through a dual-site mechanism." @default.
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- W8304782 date "1998-01-01" @default.
- W8304782 modified "2023-09-25" @default.
- W8304782 title "CHARACTERIZATION AND SELECTIVITY OF Ru/MoO3 CATALYSTS FOR THE FORMATION OF OXYGENATES FROM CO+H2. INFLUENCE OF THE TEMPERATURE OF REDUCTION." @default.
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- W8304782 doi "https://doi.org/10.1016/s0167-2991(98)80488-6" @default.
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