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- W830697335 abstract "About 15 years ago our group first discovered that ring-shaped objects were formed when a droplet of a chloroform solution of the porphyrin dimer 1 was evaporated on a carbon-coated copper grid (Fig. 8.1) [4]. Electron microscopy images revealed the presence of rings with diameters varying from 1 to 5 µm. These rings could also be imaged by confocal fluorescence microscopy, near-field scanning optical microscopy (NSOM), and atomic force microscopy (AFM) [5,6]. With the latter two techniques, the widths and heights of the rings could be estimated. In each of the individual rings these values were always very similar, and, depending on the ring size, they varied between 10 and 100 nm, corresponding to the diameter of 1-10 molecules of 1. UV-vis spectroscopy on the rings showed a red-shift of the porphyrin Soret band, suggesting the presence of head-to-tail type aggregates of porphyrins." @default.
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- W830697335 date "2012-01-01" @default.
- W830697335 modified "2023-09-23" @default.
- W830697335 title "Well-defined porphyrin architectures by self-assembly and dewetting" @default.
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- W830697335 doi "https://doi.org/10.4032/9789814364317" @default.
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