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- W831221256 abstract "Abstract The orientation relationships and interfaces between ζ′-Au5Sn and Au have been studied by transmission electron microscopy. Epitaxial Au thin films were grown on the single-crystal NaCl surfaces and Sn was evaporated to form ζ′-Au5Sn. Results showed that on both the ( 1 ¯ 11 )Au and (001)Au surfaces the (0001)ζ′ plane is the common interface surface with a common orientation relationship of ( 1 ¯ 100 )ζ′//(110)Au, which has a small misfit of 1.9%. The Au atoms have good matches across both interfaces. That δ-AuSn forms before ζ′-Au5Sn in the solid-state Au/Sn interfacial reactions was discussed by heterogeneous nucleation theory. Both phases have good orientation relationships to Au and therefore low interfacial energies. Analysis of the interfaces indicated that the ζ′-Au5Sn/Au interfacial energies should be less than δ-AuSn/Au, which favors the nucleation of ζ′-Au5Sn. However, the energy of formation of δ-AuSn is much larger, about 2.3 times, than that of ζ′-Au5Sn by data from references. Therefore δ-AuSn forms before ζ′-Au5Sn." @default.
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- W831221256 date "2015-08-01" @default.
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- W831221256 title "Orientation relationships of Au5Sn/Au interfaces and formation sequence of Au5Sn and AuSn at the Au/Sn interface" @default.
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- W831221256 doi "https://doi.org/10.1016/j.tsf.2015.06.042" @default.
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