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- W831520123 abstract "[Mn(salen) X] (X = Cl, Br and I) complexes were synthesized with yields ranging 47–56%. The H2-salen ligand and complexes were characterized by elemental analysis, 1H- and 13C NMR, UV/Vis and FTIR spectroscopies. The obtained complexes were tested as active species in the catalytic styrene epoxidation in supercritical carbon dioxide under pretty mild pressure (8.0 MPa) as solvent using either iodosylbenzene or hydrogen peroxide as oxidizing agents. Both, conversion of styrene and yield of styrene epoxide were favored as the electronegativity of the halogen ligand in the complex raised. Benzaldehyde, phenyl methyl ketone, benzoic acid, and 1-phenyl-1,2-ethanediol were other by-products detected by GC/MS together with the targeted styrene epoxide throughout the catalytic experiments. Second stage treatment in the single-pot reaction under 140 °C and 1.0 MPa did not yield the corresponding styrene carbonate, probably because an opposite trend takes place in every one of the two stages of reaction regarding the catalytic activity of the [Mn(salen)X] complex respect to the electronegativity of the halogen ligand." @default.
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- W831520123 date "2015-12-01" @default.
- W831520123 modified "2023-09-30" @default.
- W831520123 title "Effect of the halogen ligand in [Mn(salen)X] complexes on the catalytic styrene epoxidation in scCO2" @default.
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- W831520123 doi "https://doi.org/10.1016/j.jcou.2015.06.002" @default.
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