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- W831758054 abstract "The work describes EPR and 17O NMR measurements followed by theoretical calculation of the rotational correlation time <TEX>$({tau}_R)$</TEX>, the water residence time <TEX>$({tau}_m)$</TEX>, and the longitudinal electronic spin relaxation time <TEX>$(T_{le})$</TEX>(T_1e) for two new gadolinium complexes 1 and 2 of the type [<TEX>$Gd(L)(H_2O)$</TEX>] (L = tranexamic esters) in order to investigate their efficiency as a paramagnetic contrast agent (PCA). Of three correlation times, τR plays a major and predominant role to the unusually high relaxivity of 1 and 2 as compared with that of clinically approved MR CAs such as [<TEX>$Gd(DTPA)(H_2O)]2‐ (Magnevist<TEX>${circledR}$</TEX>), [Gd(DTPA-BMA)(H2O)] (Omniscan<TEX>${circledR}$</TEX>), and <TEX>$[Gd(DOTA)(H_2O)]^-$</TEX> (Dotarem<TEX>${circledR}$</TEX>). The presence of bulky tranexamic ester in the ligand seems to be responsible for the conformational rigidity, which in turn causes such great an increase in <TEX>${tau}_R$</TEX>." @default.
- W831758054 created "2016-06-24" @default.
- W831758054 date "2009-04-20" @default.
- W831758054 modified "2023-09-27" @default.
- W831758054 title "Determination of Correlation Times of New Paramagnetic Gadolinium MR Contrast Agents by EPR and<sup>17</sup>O NMR" @default.
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- W831758054 doi "https://doi.org/10.5012/bkcs.2009.30.4.849" @default.
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