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• W832562991 abstract "It has been established that a cationic rhodium(I)/BIPHEP complex catalyzes the chemo- and regioselective intermolecular cross-cyclotrimerization of silylacetylenes with unsymmetrical electron-deficient internal alkynes. Chemoselectivity was highly dependent on steric bulk of the unsymmetrical electron-deficient internal alkynes used. Two molecules of sterically less demanding alkynoates and alkynone reacted with one molecule of the silylacetylene, on the contrary, one molecule of a sterically demanding alkynoate reacted with two molecules of the silylacetylene." @default.
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• W832562991 date "2015-08-01" @default.
• W832562991 modified "2023-10-02" @default.
• W832562991 title "Cationic rhodium(I)/BIPHEP complex-catalyzed cross-cyclotrimerization of silylacetylenes and unsymmetrical electron-deficient internal alkynes" @default.
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• W832562991 doi "https://doi.org/10.1016/j.tetlet.2015.06.096" @default.
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