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• W833614329 abstract "Olivine, pyroxene,and spinel were crystallized in the ternary system anorthite-forsterite-silica to which trace amounts of the transition metal ions cr3+ , Fe2+, Mn2+, co2+, Ni 2+, and cu2+ had been added. The resulting concentrations of the transition metal ions in the liquid and crystalline phases were determined using the electron microprobe. The results, given as free energies and partition functions, indicate the order of substitution of the dipositive ions in all crystals to be Ni 2+, Co 2+, Mn 2+, cu 2+, and Fe 2+ according to the predictions of crystal field theory. The ion cr3+ substituted in greater or lesser quantities depending on the crystalline phase. The data at different temperatures permitted the calculation of the entropy function for each element. The results demonstrate that the higher concentrations of trace elements in crystals at lower temperatures are largely due to the entropy function, i.e. 4S is negative. The modification of the crystallization paths of this system by the small amounts of trace elements indicates the need for further study in this area." @default.
• W833614329 created "2016-06-24" @default.
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• W833614329 date "1971-01-01" @default.
• W833614329 modified "2023-09-27" @default.
• W833614329 title "Distribution of trace elements in olivines and proxenes - an experimental study" @default.
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• W833614329 hasPublicationYear "1971" @default.
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