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- W835284939 abstract "The cation selectivity profile of a new monocarboxylic ionophore, antibiotic-6016 has been investigated by measuring the complexation affinities for metal cations and biogenic amines as well as the cation transport activity across an organic solvent barrier. In a two phase partition study the antibiotic formed the complexes with divalent cations of 2:1 stoichiometry and the cation selectivity sequence are summarized as: Mg2+>Mn2+_??_Ca2+>Sr2+_??_Ba2+. The antibiotic was also able to complex with monovalent cations of 1:1 ionophore: cation+ stoichiometry and the complexation affinity was ranked as: NH4+_??_K+>Rb+_??_Na+>Li_??_Cs+. It is noteworthy that the antibiotic was able to complex with serotonin but was negligible for norepinephrine and histamine. In the bulk cation transport system, it efficiently trans-ported Na+, K+, Ca2+, Ba2+ and Rb+ through an CCl4 barrier layer but failed to transport Cs+ and biogenic amines. It is of great interest that the antibiotic is characterized for first time as a broad cation spectrum ionophore with a remarkable preference for Mg2+ in the naturally occurring polyether antibiotics." @default.
- W835284939 created "2016-06-24" @default.
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- W835284939 date "1979-01-01" @default.
- W835284939 modified "2023-10-03" @default.
- W835284939 title "Studies on the ionophorous antibiotics. XXIII. Ionophorous properties of antibiotic-6016, a novel magnesium selective ionophore." @default.
- W835284939 doi "https://doi.org/10.1271/bbb1961.43.1543" @default.
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