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- W84493022 abstract "Many reactants, both organic and inorganic, react with e-aq at specific rates higher than that of e-aq + H2O but slower than diffusion-controlled rates. For these, correlations have been found between the reactivity toward e-aq and the availability of a vacant orbital on the reactant. The first product of the reaction with e-aq, which contains an additional electron, may be of limited stability, but it is always formed as an intermediate. It was suggested that the electron transfer from e-aq to any reactant is an extremely fast process which is never rate determining. Consequently, those reactions which are not diffusion controlled involve pre-equilibria with reactants which have an electron configuration that allows the incorporation of an additional electron." @default.
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- W84493022 date "1965-01-01" @default.
- W84493022 modified "2023-10-07" @default.
- W84493022 title "Reactions of the Hydrated Electron" @default.
- W84493022 doi "https://doi.org/10.1021/ba-1965-0050.ch006" @default.
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