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- W845032684 abstract "Neutron diffraction measurements have been carried out at 25 °C for 9.6 mol% ⁎LiPF6-deutrerated dimethyl carbonate (DMC-d6) solutions in which the isotopic ratio of 6Li/7Li was changed. Local structure of Li+ in the solution was derived from the least squares fitting analysis of observed difference function, ΔLi(Q). It was revealed that Li+ is surrounded by ca. 3 DMC molecules and ca. 1 PF6− with intermolecular distances of r(Li+⋯O(DMC)) = 2.08 ± 0.02 Å and r(Li+⋯F(PF6−)) = 2.03 ± 0.06 Å, respectively. Raman experimental study and DFT calculations agree well with neutron structure analysis." @default.
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- W845032684 date "2016-05-01" @default.
- W845032684 modified "2023-10-02" @default.
- W845032684 title "Local structure of Li+ in concentrated LiPF6–dimethyl carbonate solutions" @default.
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- W845032684 doi "https://doi.org/10.1016/j.molliq.2015.07.004" @default.
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