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- W849585437 abstract "In the solid obtained from N-(6-methylpyridin-2-yl)mesitylenesulfonamide and acetic acid, the constituents interact via two N-H···O hydrogen bonds. The H atom situated in one of these short contacts is disordered over two positions: one of these positions is formally associated with an adduct of the neutral sulfonamide molecule and the neutral acetic acid molecule, and corresponds to a cocrystal, while the alternative site is associated with salt formation between a protonated sulfonamide molecule and deprotonated acetic acid molecule. Site-occupancy refinements and electron densities from difference Fourier maps suggest a trend with temperature, albeit of limited significance; the cocrystal is more relevant at 100 K, whereas the intensity data collected at room temperature match the description as cocrystal and salt equally well." @default.
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- W849585437 date "2015-07-07" @default.
- W849585437 modified "2023-09-26" @default.
- W849585437 title "N-(6-Methylpyridin-2-yl)mesitylenesulfonamide and acetic acid – a salt, a cocrystal or both?" @default.
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- W849585437 doi "https://doi.org/10.1107/s2053229615012826" @default.
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