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- W851852814 abstract "The acid-promoted cleavage of the E-and Z-isomers of 1-phenyl-6-neopentyl-1,3,4-trimethyl-1-silacyclohe x-3-ene(II) under various conditions gave clean and nearly quantitative formation of the ring-opened 2,3,7,7-tetramethyl-5-(X)silyl-1-octene products (X=OMe, Cl, OH). The possible mechanism for the formation of the ring-opened products was suggested that the initial protonation of II at C-4 would give a carbocation oriented so that they are to the silicon atom, and the subsequent nucleophilic attack at silicon would give rise to the observed products (VI, VII, VIII)." @default.
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- W851852814 date "1994-01-01" @default.
- W851852814 modified "2023-09-23" @default.
- W851852814 title "Acid-Promoted Ring Cleavage Reactions of Silacyclohex-3-ene Derivatives" @default.
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