Matches in SemOpenAlex for { <https://semopenalex.org/work/W852182357> ?p ?o ?g. }
- W852182357 endingPage "21" @default.
- W852182357 startingPage "15" @default.
- W852182357 abstract "Cross-Polarization with Variable Contact-time (CP-VC) is very efficient at ultra-fast MAS (νR ≥ 60 kHz) to measure accurately the dipolar interactions corresponding to C-H or N-H short distances, which are very useful for resonance assignment and for analysis of dynamics. Here, we demonstrate the CP-VC experiment with (1)H detection. In the case of C-H distances, we compare the CP-VC signals with direct ((13)C) and indirect ((1)H) detection and find that the latter allows a S/N gain of ca. 2.5, which means a gain of ca. 6 in experimental time. The main powerful characteristics of CP-VC methods are related to the ultra-fast spinning speed and to the fact that most of the time only the value of the dipolar peak separation has to be used to obtain the information. As a result, CP-VC methods are: (i) easy to set up and to use, and robust with respect to (ii) rf-inhomogeneity thus allowing the use of full rotor samples, (iii) rf mismatch, and (iv) offsets and chemical shift anisotropies. It must be noted that the CP-VC 2D method with indirect (1)H detection requires the proton resolution and is thus mainly applicable to small or perdeuterated molecules. We also show that an analysis of the dynamics can even be performed, with a reasonable experimental time, on unlabeled samples with (13)C or even (15)N natural abundance." @default.
- W852182357 created "2016-06-24" @default.
- W852182357 creator A5008243230 @default.
- W852182357 creator A5037350315 @default.
- W852182357 creator A5045816628 @default.
- W852182357 creator A5073643033 @default.
- W852182357 creator A5076717855 @default.
- W852182357 date "2016-02-01" @default.
- W852182357 modified "2023-09-25" @default.
- W852182357 title "Accurate NMR determination of C–H or N–H distances for unlabeled molecules" @default.
- W852182357 cites W1975185907 @default.
- W852182357 cites W1975417068 @default.
- W852182357 cites W1976480915 @default.
- W852182357 cites W1980295146 @default.
- W852182357 cites W1983912890 @default.
- W852182357 cites W1987799631 @default.
- W852182357 cites W1990653025 @default.
- W852182357 cites W1991214259 @default.
- W852182357 cites W2002089999 @default.
- W852182357 cites W2003886971 @default.
- W852182357 cites W2009048792 @default.
- W852182357 cites W2012007130 @default.
- W852182357 cites W2012115117 @default.
- W852182357 cites W2014256680 @default.
- W852182357 cites W2026771535 @default.
- W852182357 cites W2033174647 @default.
- W852182357 cites W2035155236 @default.
- W852182357 cites W2036849952 @default.
- W852182357 cites W2041083600 @default.
- W852182357 cites W2043464032 @default.
- W852182357 cites W2045805796 @default.
- W852182357 cites W2047255928 @default.
- W852182357 cites W2050520890 @default.
- W852182357 cites W2055463616 @default.
- W852182357 cites W2059646694 @default.
- W852182357 cites W2066294580 @default.
- W852182357 cites W2068205174 @default.
- W852182357 cites W2075501239 @default.
- W852182357 cites W2086222008 @default.
- W852182357 cites W2090607832 @default.
- W852182357 cites W2091507596 @default.
- W852182357 cites W2100591214 @default.
- W852182357 cites W2101632298 @default.
- W852182357 cites W2107746113 @default.
- W852182357 cites W2130111075 @default.
- W852182357 cites W2141168038 @default.
- W852182357 cites W2161439229 @default.
- W852182357 cites W2162884629 @default.
- W852182357 cites W2171382710 @default.
- W852182357 cites W2314956016 @default.
- W852182357 cites W2323449707 @default.
- W852182357 cites W2949551892 @default.
- W852182357 cites W4253224586 @default.
- W852182357 doi "https://doi.org/10.1016/j.ssnmr.2015.06.005" @default.
- W852182357 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26169913" @default.
- W852182357 hasPublicationYear "2016" @default.
- W852182357 type Work @default.
- W852182357 sameAs 852182357 @default.
- W852182357 citedByCount "24" @default.
- W852182357 countsByYear W8521823572015 @default.
- W852182357 countsByYear W8521823572016 @default.
- W852182357 countsByYear W8521823572017 @default.
- W852182357 countsByYear W8521823572018 @default.
- W852182357 countsByYear W8521823572019 @default.
- W852182357 countsByYear W8521823572020 @default.
- W852182357 countsByYear W8521823572021 @default.
- W852182357 countsByYear W8521823572022 @default.
- W852182357 countsByYear W8521823572023 @default.
- W852182357 crossrefType "journal-article" @default.
- W852182357 hasAuthorship W852182357A5008243230 @default.
- W852182357 hasAuthorship W852182357A5037350315 @default.
- W852182357 hasAuthorship W852182357A5045816628 @default.
- W852182357 hasAuthorship W852182357A5073643033 @default.
- W852182357 hasAuthorship W852182357A5076717855 @default.
- W852182357 hasConcept C113196181 @default.
- W852182357 hasConcept C120665830 @default.
- W852182357 hasConcept C121332964 @default.
- W852182357 hasConcept C139210041 @default.
- W852182357 hasConcept C154815118 @default.
- W852182357 hasConcept C173523689 @default.
- W852182357 hasConcept C178790620 @default.
- W852182357 hasConcept C184779094 @default.
- W852182357 hasConcept C185592680 @default.
- W852182357 hasConcept C188027245 @default.
- W852182357 hasConcept C32909587 @default.
- W852182357 hasConcept C43617362 @default.
- W852182357 hasConcept C46141821 @default.
- W852182357 hasConcept C54516573 @default.
- W852182357 hasConcept C62520636 @default.
- W852182357 hasConcept C85725439 @default.
- W852182357 hasConceptScore W852182357C113196181 @default.
- W852182357 hasConceptScore W852182357C120665830 @default.
- W852182357 hasConceptScore W852182357C121332964 @default.
- W852182357 hasConceptScore W852182357C139210041 @default.
- W852182357 hasConceptScore W852182357C154815118 @default.
- W852182357 hasConceptScore W852182357C173523689 @default.
- W852182357 hasConceptScore W852182357C178790620 @default.
- W852182357 hasConceptScore W852182357C184779094 @default.