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- W852403830 abstract "Nowadays, controlled radical polymerization (CRP) is a technique of choice for the preparation of a wide range of novel polymeric materials with well-defined molecular parameters. Metallic species have deeply marked this field of research as assessed by the development of atom transfer radical polymerization (ATRP). Besides this very successful system, another metal assisted CRP technique is emerging, i.e. organometallic-mediated radical polymerization (OMRP). In contrast to ATRP, OMRP involves the reversible formation of a covalent bond between a metal and the polymer chains, which strongly decreases the extent of termination reactions and leads to polymers with predictable molecular weights. Although many transition metals have shown ability to mediate the polymerization of vinyl monomers, 3 OMRP based on cobalt, namely the cobalt-mediated radical polymerization (CMRP), is the most efficient and versatile one. For example, the polymerization of important and quite challenging monomers like vinyl acetate (VAc), N-vinylpyrrolidone (NVP) and acrylonitrile (AN) can be properly controlled by bis(acetylacetonato)cobalt(II) (Co(acac)2). 4" @default.
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- W852403830 date "2011-04-13" @default.
- W852403830 modified "2023-09-27" @default.
- W852403830 title "Recent Advances in Macromolecular Design via Cobalt-Mediated Radical Polymerization" @default.
- W852403830 hasPublicationYear "2011" @default.
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