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- W852922486 abstract "New ferrocene-based chelate amines, (7) have been prepared. The reaction and the coordination chemistry of 4 and other related compounds (S,R)-(1-N,N-dimethylaminoethyl)-2-dicyclohexylphosphino)ferrocene (CPFA) and 1,1'-bis-(diphenylphosphino)ferrocene (BPPF) with were investigated. The reaction of the chiral ligand (S,R)-CPFA forms a complex of the type (-(S,R)-CPFA-P) (8) in which the ligand is coordinated to both rhodium centers in a monodentate fashion through phosphorus. In contrast, the bisphosphine analogues such as BPPF and 4 afford chelate complexes of the type ( (9 & 10) where both ligands act as a chelate bidentate to a single rhodium atom. All these complexes were characterized by microanalytical and spectroscopic techniques. In one case, the structure of 8 was determined by X-ray crystallography. Crystals are monoclinic, space group C2 (No. 5), with a=26.389 (3), b=12.942 (1), c=11.825 (1) A, =111.22(1), V=3964.7 (8) , Z=4, and =1.58 g . Two Rh(II) centers are bridged by four groups in the : mode across a Rh-Rh single bond, and octahedral coordination at Rh(1) and Rh(1') is completed by axially coordinating (S,R)-CPFA and a briding , respectively." @default.
- W852922486 created "2016-06-24" @default.
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- W852922486 date "1994-01-01" @default.
- W852922486 modified "2023-09-23" @default.
- W852922486 title "Synthesis and Reaction Chemistry of Some Ferrocene-Containing Chelate Ligands with Dirhodium Acetate: X-ray Crystal Structure of $(eta^1-(S,R)-CPFA)_2Rh_2(OAc)_4$" @default.
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