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• W85383005 abstract "The title two-dimensional hydrogen-bonded coordination com­pounds, [Cu(C8H5O4)2(C4H6N2)2], (I), and [Cu(C8H7O2)2(C4H6N2)2]·H2O, (II), have been synthesized and structurally characterized. The mol­ecule of complex (I) lies across an inversion centre, and the Cu2+ ion is coordinated by two N atoms from two 4-methyl-1H-imidazole (4-MeIM) mol­ecules and two O atoms from two 3-carboxy­benzoate (HBDC−) anions in a square-planar geometry. Adjacent mol­ecules are linked through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds into a two-dimensional sheet with (4,4) topology. In the asymmetric part of the unit cell of (II) there are two symmetry-independent mol­ecules, in which each Cu2+ ion is also coordinated by two N atoms from two 4-MeIM mol­ecules and two O atoms from two 3-methyl­benzoate (3-MeBC−) anions in a square-planar coordination. Two neutral complex mol­ecules are held together via N—H⋯O(carboxyl­ate) hydrogen bonds to generate a dimeric pair, which is further linked via discrete water mol­ecules into a two-dimensional network with the Schläfli symbol (43)2(46,66,83). In both compounds, as well as the strong intermolecular hydrogen bonds, π–π interactions also stabilize the crystal stacking." @default.
• W85383005 created "2016-06-24" @default.
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• W85383005 date "2009-11-25" @default.
• W85383005 modified "2023-10-16" @default.
• W85383005 title "Two two-dimensional hydrogen-bonded coordination networks: bis(3-carboxybenzoato-κ<i>O</i>)bis(4-methyl-1<i>H</i>-imidazole-κ<i>N</i>³)copper(II) and bis(3-methylbenzoato-κ<i>N</i>)bis(4-methyl-1<i>H</i>-imidazole-κ<i>N</i>³)copper(II) monohydrate" @default.
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• W85383005 doi "https://doi.org/10.1107/s0108270109048203" @default.
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