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- W855394071 abstract "Five new isocyano/isothiocyanato sesquiterpenes (1-5) with tri- or bicyclic carbon skeletons have been characterized from Australian specimens of the nudibranch Phyllidia ocellata. Spectroscopic analyses at 900 MHz were informed by DFT calculations. The 1S, 5S, 8R configuration of 2-isocyanoclovene (1) was determined by X-ray crystallographic analysis of formamide 6. A biosynthetic pathway to clovanes 1 and 2 from epicaryolane precursors is proposed. Isocyanides 1, 2, and 4 showed activity against Plasmodium falciparum (IC50 0.26-0.30 μM), while isothiocyanate 3 and formamide 6 had IC50 values of >10 μM." @default.
- W855394071 created "2016-06-24" @default.
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- W855394071 date "2015-06-09" @default.
- W855394071 modified "2023-10-14" @default.
- W855394071 title "Antimalarial Isocyano and Isothiocyanato Sesquiterpenes with Tri- and Bicyclic Skeletons from the Nudibranch <i>Phyllidia ocellata</i>" @default.
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- W855394071 doi "https://doi.org/10.1021/acs.jnatprod.5b00354" @default.
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