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- W857804906 abstract "Combustion of fuels, including renewable fuels, is associated with emissions of various gaseous compounds containing chlorine. The reversible sorption / desorption of hydrogen chloride, in a fluidized bed reactor, while combustion of Cl-containing substances, was carried out. Dichloromethane (DCM) was used as the source of chlorine. DCM thermal decomposition in a sand bed and then in a fluidized bed containing hydroxyapatite was investigated. In both series: process temperature was 930oC, the air excess 1.3, the concentration of DCM 2900 ppm. The concentration of components containing chlorine such as HCl, CH2Cl2, CH3Cl, CHCl3, CCl4, COCl2 in the flue gases were monitored by FTIR analyzer. The main chlorine product was HCl. Samples of the hydroxyapatite before the process of thermal decomposition of DCM, taken from the bed during the process, and after the thermal decomposition of chlorapatite at 1050°C were analyzed by X-ray diffraction (XRD). The content of chlorapatite in the analyzed samples was respectively 10, 53 and 18%. X-ray fluorescence (XRF) analysis showed the molar ratio of Ca:P:Cl was: 1.12:0.41:0.01, 1.01:0.36:0.09, 1.10:0.40:0.05 respectively. The hydroxyapatite can be used as an absorbent of the HCl(g) during combustion of materials containing chlorine." @default.
- W857804906 created "2016-06-24" @default.
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- W857804906 date "2014-01-01" @default.
- W857804906 modified "2023-09-26" @default.
- W857804906 title "Thermal decomposition of selected chlorinated aliphatic hydrocarbons in the fluidized bed reactor with chemically active bed material" @default.
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- W857804906 doi "https://doi.org/10.2429/proc.2014.8(1)009" @default.
- W857804906 hasPublicationYear "2014" @default.
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