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• W85830614 abstract "The structure of the title compound, tripotassium trans-tetra­cyanidodioxidotechnetate(V), is isotypic with its Re analogue. The [TcO2(CN)4]3− trans-tetra­cyanido­dioxido­technetate anion has a slightly distorted octa­hedral configuration. The Tc atom is located on a center of inversion and is bound to two O atoms in axial and to four cyanide ligands in equatorial positions. The Tc—O distance is consistent with a double-bond character. The two potassium cations, one located on a center of inversion and one in a general position, reside in octa­hedral or tetra­hedral environments, respectively. K⋯O and K⋯N inter­actions occur in the 2.7877 (19)–2.8598 (15) Å range." @default.
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• W85830614 date "2010-07-21" @default.
• W85830614 modified "2023-09-23" @default.
• W85830614 title "<i>trans</i>-K₃[TcO₂(CN)₄]" @default.
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• W85830614 doi "https://doi.org/10.1107/s1600536810028205" @default.
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