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- W858523162 abstract "Calorimetric titrations were performed in anhydrous acetonitrile at 298.15 K,giving the com-plex stability constants(K_s)and the thermodynamic parameters for the complexation of the rare earth ni-trates(La～Er,Yb)with N-benzylmonoaza-18-crown-6(18-C-6).Thermodynamic quantities clearly in-dicate that the coordination stability of the arm-type 18-crown-6 with the lanthanoid nitrates increasesfrom Ce to Gd,and decreases slightly from Gd to Tb with increasing atomic number.The coordination of thearm-type 18-C-6 with Gd shows the stonger complexation ability and selectivity.Thermodynamically theformation of the complexes is evidently driven by enthalpy,but the complexes stability sequence is essentiallyentropy governed." @default.
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- W858523162 date "1993-01-01" @default.
- W858523162 modified "2023-09-24" @default.
- W858523162 title "Calorimetric Titration of Complexation of the N-benzylmonoaza-18-Crown-6 with Rare Earth(III)Nitrates in Anhydrous Acetonitrile" @default.
- W858523162 hasPublicationYear "1993" @default.
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